Control of quantum phenomena: Past, present, and future

Quantum control is concerned with active manipulation of physical and chemical processes on the atomic and molecular scale. This work presents a perspective of progress in the field of control over quantum phenomena, tracing the evolution of theoretical concepts and experimental methods from early developments to the most recent advances. The current experimental successes would be impossible without the development of intense femtosecond laser sources and pulse shapers. The two most critical theoretical insights were (1) realizing that ultrafast atomic and molecular dynamics can be controlled via manipulation of quantum interferences and (2) understanding that optimally shaped ultrafast laser pulses are the most effective means for producing the desired quantum interference patterns in the controlled system. Finally, these theoretical and experimental advances were brought together by the crucial concept of adaptive feedback control, which is a laboratory procedure employing measurement-driven, closed-loop optimization to identify the best shapes of femtosecond laser control pulses for steering quantum dynamics towards the desired objective. Optimization in adaptive feedback control experiments is guided by a learning algorithm, with stochastic methods proving to be especially effective. Adaptive feedback control of quantum phenomena has found numerous applications in many areas of the physical and chemical sciences, and this paper reviews the extensive experiments. Other subjects discussed include quantum optimal control theory, quantum control landscapes, the role of theoretical control designs in experimental realizations, and real-time quantum feedback control. The paper concludes with a prospective of open research directions that are likely to attract significant attention in the future.Comment: Review article, final version (significantly updated), 76 pages, accepted for publication in New J. Phys. (Focus issue: Quantum control

Quantum Multiobservable Control

We present deterministic algorithms for the simultaneous control of an arbitrary number of quantum observables. Unlike optimal control approaches based on cost function optimization, quantum multiobservable tracking control (MOTC) is capable of tracking predetermined homotopic trajectories to target expectation values in the space of multiobservables. The convergence of these algorithms is facilitated by the favorable critical topology of quantum control landscapes. Fundamental properties of quantum multiobservable control landscapes that underlie the efficiency of MOTC, including the multiobservable controllability Gramian, are introduced. The effects of multiple control objectives on the structure and complexity of optimal fields are examined. With minor modifications, the techniques described herein can be applied to general quantum multiobjective control problems.Comment: To appear in Physical Review

Quantum Control Landscapes

Numerous lines of experimental, numerical and analytical evidence indicate that it is surprisingly easy to locate optimal controls steering quantum dynamical systems to desired objectives. This has enabled the control of complex quantum systems despite the expense of solving the Schrodinger equation in simulations and the complicating effects of environmental decoherence in the laboratory. Recent work indicates that this simplicity originates in universal properties of the solution sets to quantum control problems that are fundamentally different from their classical counterparts. Here, we review studies that aim to systematically characterize these properties, enabling the classification of quantum control mechanisms and the design of globally efficient quantum control algorithms.Comment: 45 pages, 15 figures; International Reviews in Physical Chemistry, Vol. 26, Iss. 4, pp. 671-735 (2007

General unifying features of controlled quantum phenomena

Many proposals have been put forth for controlling quantum phenomena, including open-loop, adaptive feedback, and real-time feedback control. Each of these approaches has been viewed as operationally, and even physically, distinct from the others. This work shows that all such scenarios inherently share the same fundamental control features residing in the topology of the landscape relating the target physical observable to the applied controls. This unified foundation may provide a basis for development of hybrid control schemes that would combine the advantages of the existing approaches to achieve the best overall performance.Comment: The published version (includes the supplementary material